Influence of Boron, Tungsten and Molybdenum Modifiers on Zirconia Based Pt Catalyst for Glycerol Valorization.

ABSTRACT: The influence of boron, tungsten and molybdenum modifiers on zirconia-based Pt catalyst was studied for glycerol valorization. Zirconia modified supports were prepared by impregnation of ZrO₂ with either boric, silicontungstic or phosphomolybdic acids to obtain supports with enhanced Brönsted acidic properties. The modified supports were subsequently impregnated with chloroplatinic acid to obtain Pt-based catalysts. Pt incorporation resulted in the increase in Lewis acidity of the solids, being more significant for the Pt//W/ZrO₂ catalyst. Reduced Pt catalysts were tested for the liquid-phase glycerol hydrogenolysis, observing a synergistic effect between catalyst acid sites and metal function that proved to be crucial in glycerol hydrogenolysis. The Pt//W/ZrO₂ catalyst was the most active

SUBMITTER: Checa M 

PROVIDER: S-EPMC6523238 | biostudies-literature | 2019 Apr

REPOSITORIES: biostudies-literature