Dataset of polyoxometalate-assisted N-heterocyclic carbene gold(I) complexes.

ABSTRACT: The present paper is the Supplemental materials for our original paper entitled "highly active, homogeneous catalysis by polyoxometalate-assisted N-heterocyclic carbene gold(I) complexes for hydration of diphenylacetylene. The present article refers to the preparations of several monomeric, N-heterocyclic (NHC) carbene/carboxylate (RS-pyrrld)/gold(I) complexes, [Au(RS-pyrrld)(NHC)] (NHC = IMes (6), BIPr (7), IF³ (8), I^tBu (9)), which were used for homogenous catalysis of the hydration reaction of diphenylacetylene to afford deoxybenzoin. The article also includes the preparations of the precursor complexes, [AuCl(NHC)] (NHC = IPr, IMes, BIPr, IF³, I^tBu), and novel X-ray crystallography of th

SUBMITTER: Nomiya K 

PROVIDER: S-EPMC6557754 | biostudies-literature | 2019 Aug

REPOSITORIES: biostudies-literature