Chemically modified nanofoci unifying plasmonics and catalysis.

ABSTRACT: A plasmonic nanofocus, often in the form of a nanogap, is capable of concentrating light in a nanometric volume. The greatly enhanced electromagnetic field offers many opportunities in physics and chemistry. However, the lack of a method to fine-tune the chemical activities of the nanofocus has severely limited its application. Here we communicate an intriguing class of chemically modified nanofoci (CMNFs) that are able to address this challenge. Our results successfully demonstrate a possibility to functionalize the nanosized, mass-transport-restricted nanogap (nanofocus) of a dimeric gold nanoparticle assembly with homo-(Au) and heterogeneous (Ag, Pt, and Pd) materials. The as-produced structures with conductive Au and Ag junctions generate a novel form of charge transfer plasmon (CTP) w

SUBMITTER: Wang Y 

PROVIDER: S-EPMC6582755 | biostudies-literature | 2019 Jun

REPOSITORIES: biostudies-literature