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Non-Porous versus Mesoporous Siliceous Materials for CO₂ Capture.

ABSTRACT: In this study, the adsorption properties of a Stöber silica-based material towards CO₂ were evaluated for the first time. The use of Stöber silica as support is interesting for real technological applications mainly due to economic factors. Furthermore, a direct comparison between the non porous Stöber sample with an ordered porous material (based on MCM-41 silica) allowed to evaluate the effect of the porosity on the CO₂ adsorption properties. In order to make silica materials reactive towards CO₂, they were functionalized by introducing amino groups via grafting of 3-[2-(2-aminoethyl)aminoethyl]aminopropyltrimethoxysilane. After a qualitative study of the CO₂ adsorption, the quantitative determination of CO₂ adsorption capacity at 35 °C revealed that the mesoporous material is more efficient compared to the Stöber-based one (adsorption capacity values of 0.49 and 0.58 mol/kg for Stöber-based and mesoporous samples). However, since the difference in the adsorption capacity is only about 15 % and the Stöber-based sample is considerably cheaper, the non-porous sample should be considered as a favourable adsorbent material for CO₂ capture applications.

SUBMITTER: Vittoni C

PROVIDER: S-EPMC6587325 | biostudies-literature | 2019 Jun

REPOSITORIES: biostudies-literature

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Non-Porous versus Mesoporous Siliceous Materials for CO2 Capture.

Vittoni Chiara C Gatti Giorgio G Paul Geo G Mangano Enzo E Brandani Stefano S Bisio Chiara C Marchese Leonardo L

ChemistryOpen 20190527 6

In this study, the adsorption properties of a Stöber silica-based material towards CO2 were evaluated for the first time. The use of Stöber silica as support is interesting for real technological applications mainly due to economic factors. Furthermore, a direct comparison between the non porous Stöber sample with an ordered porous material (based on MCM-41 silica) allowed to evaluate the effect of the porosity on the CO2 adsorption properties. In order to make silica mater ...[more]

PMID: 31275793

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Project description:CO2 capture via physical adsorption on activated porous carbons represents a promising solution towards effective carbon emission mitigation. Additionally, production costs can be further decreased by utilising biomass as the main precursor and applying energy-efficient activation. In this work, we developed novel cellulose-based activated carbons modified with amines (diethylenetriamine (DETA), 1,2-bis(3-aminopropylamino)ethane (BAPE), and melamine (MELA)) with different numbers of nitrogen atoms as in situ N-doping precursors. We investigated the effect of hydrothermal and thermal activation on the development of their physicochemical properties, which significantly influence the resulting CO2 adsorption capacity. This process entailed an initial hydrothermal activation of biomass precursor and amines at 240 °C, resulting in C+DETA, C+BAPE and C+MELA materials. Thermal samples (C+DETA (P), C+BAPE (P), and C+MELA (P)) were synthesised from hydrothermal materials by subsequent KOH chemical activation and pyrolysis in an inert argon atmosphere. Their chemical and structural properties were characterised using elemental analysis (CHN), infrared spectroscopy (IR), scanning electron microscopy (SEM), and thermogravimetric analysis (TG). The calculated specific surface areas (SBET) for thermal products showed higher values (998 m2 g-1 for C+DETA (P), 1076 m2 g-1 for C+BAPE (P), and 1348 m2 g-1 for C+MELA (P)) compared to the hydrothermal products (769 m2 g-1 for C+DETA, 833 m2 g-1 for C+BAPE, and 1079 m2 g-1 for C+MELA). Carbon dioxide adsorption as measured by volumetric and gravimetric methods at 0 and 25 °C, respectively, showed the opposite trend, which can be attributed to the reduced content of primary adsorption sites in the form of amine groups in thermal products. N2 and CO2 adsorption measurements were carried out on hydrothermal (C) and pyrolysed cellulose (C (P)), which showed a several-fold reduction in adsorption properties compared to amine-modified materials. The recyclability of C+MELA, which showed the highest CO2 adsorption capacity (7.34 mmol g-1), was studied using argon purging and thermal regeneration over five adsorption/desorption cycles.

Dataset Information

Non-Porous versus Mesoporous Siliceous Materials for CO₂ Capture.

Publications

Non-Porous versus Mesoporous Siliceous Materials for CO<sub>2</sub> Capture.

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