Bis phenylene flattened 13-membered tetraamide macrocyclic ligand (TAML) for square planar cobalt(III).

ABSTRACT: The preparation, characterization, and evaluation of a cobalt(III) complex with 13-membered tetraamide macrocyclic ligand (TAML) is described. This is a square-planar (X-ray) S = 1 paramagnetic (¹H NMR) compound, which becomes an S = 0 diamagnetic octahedral species in excess d₅-pyridine. Its one-electron oxidation at an electrode is fully reversible with the lowest E _1/2 value (0.66 V vs SCE) among all investigated Co^III TAML complexes. The oxidation results in a neutral blue species which is consistent with a Co^III/radical-cation ligand. The ease of oxidation is likely due to the two benzene rings incorporated in the ligand structure (whereas there is just one in many other Co^III TAMLs). The oxi

SUBMITTER: Ellis WC 

PROVIDER: S-EPMC6596426 | biostudies-literature | 2018

REPOSITORIES: biostudies-literature