Hydro/Deutero Deamination of Arylazo Sulfones under Metal- and (Photo)Catalyst-Free Conditions.

ABSTRACT: Hydrodeaminated and monodeuterated aromatics were obtained via a visible-light driven reaction of arylazo sulfones. Deuteration occurs efficiently in deuterated media such as isopropanol-d8 or in THF-d8/water mixtures and exhibits a high tolerance to the nature and the position of the aromatic substituents.

SUBMITTER: Amin HIM 

PROVIDER: S-EPMC6601019 | biostudies-literature | 2019 Jun

REPOSITORIES: biostudies-literature