Tuning charge transport dynamics via clustering of doping in organic semiconductor thin films.

ABSTRACT: A significant challenge in the rational design of organic thermoelectric materials is to realize simultaneously high electrical conductivity and high induced-voltage in response to a thermal gradient, which is represented by the Seebeck coefficient. Conventional wisdom posits that the polymer alone dictates thermoelectric efficiency. Herein, we show that doping - in particular, clustering of dopants within conjugated polymer films - has a profound and predictable influence on their thermoelectric properties. We correlate Seebeck coefficient and electrical conductivity of iodine-doped poly(3-hexylthiophene) and poly[2,5-bis(2-octyldodecyl)pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione-3,6-diyl)-alt-(2,2';5',2'';5'',2'''-quaterthiophen-5,5'''-diyl)] films with Kelvin probe force microscopy to highli

SUBMITTER: Boyle CJ 

PROVIDER: S-EPMC6610129 | biostudies-literature | 2019 Jul

REPOSITORIES: biostudies-literature