Sorption, persistence, and leaching of the allelochemical umbelliferone in soils treated with nanoengineered sorbents.

ABSTRACT: Coumarins represent an important family of allelochemicals with fungicidal, bactericidal, insecticidal, nematicidal, and herbicidal properties. Like for other allelochemicals, the short persistence of coumarins in soils can reduce their biological activity and hamper their application as environmentally friendly agrochemicals. We evaluated the sorption of the coumarin umbelliferone by eight soils and six sorbent materials, and then selected two nanoengineered sorbents, hexadecyltrimethylammonium-modified Arizona montmorillonite (SA-HDTMA) and olive-mill waste biochar (BC), to assess the effect of their addition to two distinct soils on umbelliferone sorption, persistence, and leaching. Umbelliferone was sorbed to a greater extent by the acid soils (A1-A2, K_d > 4.0 L kg^-1

SUBMITTER: Real M 

PROVIDER: S-EPMC6611869 | biostudies-literature | 2019 Jul

REPOSITORIES: biostudies-literature