Small Alkaline-Earth-based Core/Shell Nanoparticles for Efficient Upconversion.

ABSTRACT: The optical efficiency of lanthanide-based upconversion is intricately related to the crystalline host lattice. Different crystal fields interacting with the electron clouds of the lanthanides can significantly affect transition probabilities between the energy levels. Here, we investigate six distinct alkaline-earth rare-earth fluoride host materials (M_{1- x}Ln _xF_2+x, MLnF) for infrared-to-visible upconversion, focusing on nanoparticles of CaYF, CaLuF, SrYF, SrLuF, BaYF, and BaLuF doped with Yb³⁺ and Er³⁺. We first synthesize ∼5 nm upconverting cores of each material via a thermal decomposition method. Then we introduce a dropwise hot-injection method to grow optically inert MYF shell layers around the active cores. Five distinct shell

SUBMITTER: Fischer S 

PROVIDER: S-EPMC6613352 | biostudies-literature | 2019 Jun

REPOSITORIES: biostudies-literature