Interplay of Fluorescence and Phosphorescence in Organic Biluminescent Emitters.

ABSTRACT: Biluminescent organic emitters show simultaneous fluorescence and phosphorescence at room temperature. So far, the optimization of the room-temperature phosphorescence in these materials has drawn the attention of research. However, the continuous-wave operation of these emitters will consequently turn them into systems with vastly imbalanced singlet and triplet populations, which is due to the respective excited-state lifetimes. This study reports on the exciton dynamics of the biluminophore NPB (N,N'-di(1-naphthyl)-N,N'-diphenyl-(1,1-biphenyl)-4,4-diamine). In the extreme case, the singlet and triplet exciton lifetimes stretch from 3 ns to 300 ms, respectively. Through sample engineering and oxygen quenching experiments, the triplet exciton density can be cont

SUBMITTER: Salas Redondo C 

PROVIDER: S-EPMC6614881 | biostudies-literature | 2017 Jul

REPOSITORIES: biostudies-literature