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Mechanisms of Adsorption of Heavy Metal Cations from Waters by an Amino Bio-Based Resin Derived from Rosin.


ABSTRACT: Rosin derived from conifer trees is used as the basis for a novel environmentally-friendly adsorbent prepared from a sustainable resource. After treatment with ethylenediamine, ethylenediamine rosin-based resin (EDAR) is produced, which possesses cation exchange capacity that is comparable to that of the best commercial synthetic resins. This is demonstrated by its application to the removal of Pb, Cd, and Cu from water, in single and multicomponent systems. Maximum uptake was obtained at pH 5 and in the order Pb(II) > Cd(II) > Cu(II). The maximum adsorption of Pb was ~1.8 mmol/g, but the adsorption process resembled the Freundlich isotherm, whereas the adsorption of Cd(II) and Cu(II) followed the Langmuir isotherm. In the multicomponent systems, there was direct competition between Pb and

SUBMITTER: Huang W 

PROVIDER: S-EPMC6630295 | biostudies-literature | 2019 Jun

REPOSITORIES: biostudies-literature