An Asymmetrically Substituted Aliphatic Bis-Dithiolene Mono-Oxido Molybdenum(IV) Complex With Ester and Alcohol Functions as Structural and Functional Active Site Model of Molybdoenzymes.

ABSTRACT: A Mo^IV mono-oxido bis-dithiolene complex, [MoO(mohdt)₂]^2- (mohdt = 1-methoxy-1-oxo-4-hydroxy-but-2-ene-2,3-bis-thiolate) was synthesized as a structural and functional model for molybdenum oxidoreductase enzymes of the DMSO reductase family. It was comprehensively characterized by inter alia various spectroscopic methods and employed as an oxygen atom transfer (OAT) catalyst. The ligand precursor of mohdt was readily prepared by a three-step synthesis starting from dimethyl-but-2-ynedioate. Crystallographic and ¹³C-NMR data support the rationale that by asymmetric substitution the electronic structure of the ene-dithio moiety can be fine-tuned. The Mo^IVO bis-dithiolene complex was obtained by in situ reaction of the de-pr

SUBMITTER: Ahmadi M 

PROVIDER: S-EPMC6637267 | biostudies-literature | 2019

REPOSITORIES: biostudies-literature