Remote Charge Effects on the Oxygen-Atom-Transfer Reactivity and Their Relationship to Molybdenum Enzymes.

ABSTRACT: We report the syntheses, crystal structures, and characterization of the novel cis-dioxomolybdenum(VI) complexes [Tpm*Mo^VIO₂Cl](MoO₂Cl₃) (1) and [Tpm*Mo^VIO₂Cl](ClO₄) (2), which are supported by the charge-neutral tris(3,5-dimethyl-1-pyrazolyl)methane (Tpm*) ligand. A comparison between isostructural [Tpm*Mo^VIO₂Cl]⁺ and Tp*Mo^VIO₂Cl [Tp* = hydrotris(3,5-dimethyl-1-pyrazolyl)borate] reveals the effects of one unit of overall charge difference on their spectroscopic and electrochemical properties, geometric and electronic structures, and O-atom-transfer (OAT) reactivities, providing new insight into pyranopterin molybdoenzyme OAT reactivity. Computational studies

SUBMITTER: Paudel J 

PROVIDER: S-EPMC6639825 | biostudies-literature | 2019 Feb

REPOSITORIES: biostudies-literature