Rhenium(I)-Based Monocyclic and Bicyclic Phosphine Oxide-Coordinated Supramolecular Complexes.

ABSTRACT: Neutral, flexible ditopic phosphine (P-P) or phosphine oxide (O=P-P=O) donors, rigid anionic bis-chelating oxygen donors, and Re₂(CO)₁₀ were used to assemble ten phosphine oxide (P=O)-donor-based neutral monocyclic M₂LL'-, bicyclic M₄L₂L″-, and bicyclic M₄LL'₂-type supramolecular coordination complexes (SCCs). A soft ditopic phosphine donor was transformed into a hard ditopic phosphine oxide donor, during the formation of the cyclic complexes 1-3, 5-6, and 9-10. Complexes 4, 7, and 8 were obtained using a hard P=O donor ligand. These SCCs were characterized using elemental analysis, FTIR, NMR, and single-crystal X-ray diffraction analysis. The absorpti

SUBMITTER: Shankar B 

PROVIDER: S-EPMC6640797 | biostudies-literature | 2016 Oct

REPOSITORIES: biostudies-literature