Zirconium Oxynitride-Catalyzed Oxygen Reduction Reaction at Polymer Electrolyte Fuel Cell Cathodes.

ABSTRACT: Most nonplatinum group metal (non-PGM) catalysts for polymer electrolyte fuel cell cathodes have so far been limited to iron(cobalt)/nitrogen/carbon [Fe(Co)/N/C] composites owing to their high activity in both half-cell and single-cell cathode processes. Group IV and V metal oxides, another class of non-PGM catalysts, are stable in acidic media; however, their activities have been mostly evaluated for half-cells, with no single-cell performances comparable to those of Fe/N/C composites reported to date. Herein, we report successful syntheses of zirconium oxynitride catalysts on multiwalled carbon nanotubes, which show the highest oxygen reduction reaction activity among oxide-based catalysts. The single-cell performance of these catalysts reached 10 mA cm^-2 at 0.9 V, being compa

SUBMITTER: Chisaka M 

PROVIDER: S-EPMC6640960 | biostudies-literature | 2017 Feb

REPOSITORIES: biostudies-literature