Platinum Complexes with Chelating Acyclic Aminocarbene Ligands Work as Catalysts for Hydrosilylation of Alkynes.

ABSTRACT: This work describes the preparation of a series of platinum-aminocarbene complexes [PtCl{C(N=C ^a (C₆R²R³R⁴R⁵CON ^b ))=N(H)R¹}(CNR¹)] ^a-b (8-19, 65-75% isolated yield) via the reaction of cis-[PtCl₂(CNR¹)₂] (R¹ = Cy 1, t-Bu 2, Xyl 3, 2-Cl-6-MeC₆H₃ 4) with 3-iminoisoindolin-1-ones HN=C ^a (C₆R²R³R⁴R⁵CON ^b H) (R²-R⁵ = H 5; R³ = Me, R², R⁴, R⁵ = H 6; R³, R⁴

SUBMITTER: Chay RS 

PROVIDER: S-EPMC6641237 | biostudies-literature | 2018 Jan

REPOSITORIES: biostudies-literature