Ni-Sn-Supported ZrO₂ Catalysts Modified by Indium for Selective CO₂ Hydrogenation to Methanol.

ABSTRACT: Ni and NiSn supported on zirconia (ZrO₂) and on indium (In)-incorporated zirconia (InZrO₂) catalysts were prepared by a wet chemical reduction route and tested for hydrogenation of CO₂ to methanol in a fixed-bed isothermal flow reactor at 250 °C. The mono-metallic Ni (5%Ni/ZrO₂) catalysts showed a very high selectivity for methane (99%) during CO₂ hydrogenation. Introduction of Sn to this material with the following formulation 5Ni5Sn/ZrO₂ (5% Ni-5% Sn/ZrO₂) showed the rate of methanol formation to be 0.0417 μmol/(g_cat·s) with 54% selectivity. Furthermore, the combination NiSn supported on InZrO₂ (5Ni5Sn/10InZrO₂) exhibited a rate of methanol formation 10 times higher than that on

SUBMITTER: Hengne AM 

PROVIDER: S-EPMC6641425 | biostudies-literature | 2018 Apr

REPOSITORIES: biostudies-literature