Hierarchically Porous Zirconia Monolith Fabricated from Bacterial Cellulose and Preceramic Polymer.

ABSTRACT: A hierarchically porous zirconia (ZrO₂) monolith was successfully fabricated by using bacterial cellulose (BC) as a biotemplate and preceramic polymer as a zirconium resource, via freeze-drying and two-step calcination process. Images of scanning electron microscopy showed that the ZrO₂ monolith well-replicated a three-dimensional reticulated structure of pristine BC and possessed good morphology stability till 1100 °C in air. Results of N₂ adsorption/desorption and mercury porosimetry analysis revealed the hierarchically porous structure and large specific area (9.7 m²·g^-1) of the ZrO₂ monolith, respectively. Patterns of X-ray powder diffraction indicated that the monoclinic phase and tetragonal phase coexisted in the ZrO

SUBMITTER: Zhang BX 

PROVIDER: S-EPMC6641484 | biostudies-literature | 2018 Apr

REPOSITORIES: biostudies-literature