Photocatalytic Dehydrogenation of Primary Alcohols: Selectivity Goes against Adsorptivity.

ABSTRACT: Solid/liquid heterogeneous photocatalysis was often considered to occur on the active sites of a solid catalyst surface. Herein, we report that the selectivity of photocatalytic dehydrogenative oxidations of aliphatic primary alcohols in acetonitrile solution into corresponding aldehydes exhibits an anomalous relationship with adsorption behavior of the alcohols. By using Pt-loaded TiO₂ photocatalyst in an inert atmosphere under UV light illumination, primary short-chain alcohols (SCAs) with strong adsorption were dehydrogenated into aldehydes in very poor selectivity, whereas weak-adsorbable long-chain alcohols (LCAs) were transformed into corresponding aldehydes with much higher selectivity. More than 20 examples of primary LCAs (C₄-C₁₀) were successfully

SUBMITTER: Ma D 

PROVIDER: S-EPMC6641877 | biostudies-literature | 2017 Aug

REPOSITORIES: biostudies-literature