Iron^III Half Salen Catalysts for Atom Transfer Radical and Ring-Opening Polymerizations.

ABSTRACT: A series of monometallic pentacoordinate Fe^III chloride complexes have been prepared and characterized by high-resolution mass spectrometry and elemental analysis. X-ray diffraction analysis showed that the bis-chelated Fe^III complexes bear distorted trigonal bipyramidal geometries. The air- and moisture-stable Fe^III complexes were screened as mediators in the reverse atom transfer radical polymerization (ATRP) of styrene and methyl methacrylate. Moderate to excellent control was achieved with dispersities as low as 1.1 for both poly(methyl methacrylate) and polystyrene. Kinetic studies showed living characteristics, and end group analysis revealed the presence of olefin-terminated polymer chains, suggesting catalytic chain transfer as a competing polymeriz

SUBMITTER: Fazekas E 

PROVIDER: S-EPMC6643736 | biostudies-literature | 2018 Dec

REPOSITORIES: biostudies-literature