Dataset Information

{CpFe^II(CO)₂Sn^II(Macrocycle^•3-)} Radicals with Intrinsic Charge Transfer from CpFe(CO)₂ to Macrocycles (Cp: Cp or Cp*); Effective Magnetic Coupling between Radical Trianionic Macrocycles^•3.

ABSTRACT: Neutral {CpFe^II(CO)₂[Sn^II(Pc^•3-)]} {Cp is cyclopentadienyl (1, 2) or Cp* is pentamethylcyclopentadienyl (3); Pc: phthalocyanine}, {Cp*Fe^II(CO)₂[Sn^II(Nc^•3-)]} (4, Nc: naphthalocyanine), and {CpFe^II(CO)₂[Sn^II(TPP^•3-)]} (5, TPP: tetraphenylporphyrin) complexes in which CpFe^II(CO)₂ fragments (Cp: Cp or Cp*) are coordinated to Sn^II(macrocycle^•3-) have been obtained. The product complexes were obtained at the reaction of charge transfer from CpFe^I(CO)₂ (Cp: Cp or Cp*) to [Sn^II(macrocycle^2-)] to form the diamagnetic Fe^II and paramagnet

SUBMITTER: Konarev DV

PROVIDER: S-EPMC6644027 | biostudies-literature | 2018 Nov

REPOSITORIES: biostudies-literature

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Dataset Information

{CpFe^II(CO)₂Sn^II(Macrocycle^•3-)} Radicals with Intrinsic Charge Transfer from CpFe(CO)₂ to Macrocycles (Cp: Cp or Cp*); Effective Magnetic Coupling between Radical Trianionic Macrocycles^•3.

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Dataset Information

{CpFeII(CO)2SnII(Macrocycle•3-)} Radicals with Intrinsic Charge Transfer from CpFe(CO)2 to Macrocycles (Cp: Cp or Cp*); Effective Magnetic Coupling between Radical Trianionic Macrocycles•3.

OmicsDI is part of the ELIXIR infrastructure

Tweets

{CpFe^II(CO)₂Sn^II(Macrocycle^•3-)} Radicals with Intrinsic Charge Transfer from CpFe(CO)₂ to Macrocycles (Cp: Cp or Cp*); Effective Magnetic Coupling between Radical Trianionic Macrocycles^•3.