Flow-Induced Precursor Formation of Poly(l-lactic acid) under Pressure.

ABSTRACT: For the first time, the influences of two inevitable processing fields (pressure and flow fields) on the crystallization of a semirigid molecular chain polymer, that is, poly(l-lactic acid) (PLLA), were explored using a homemade pressuring and shearing device. The results reveal that the shear rate facilitated the generation of precursor because it induced oriented segment formation. It was found that the most sensitive shear temperature for the generation of PLLA precursor under 100 MPa was 180 °C. When the shear temperature was higher (e.g., 190 °C), the relaxation of shear-induced oriented segments was too quick to induce the generation of PLLA precursor. Oppositely, at a lower shear temperature (170 °C), the oriented segments were hard to relax within the whole shear rate range (3.1-31

SUBMITTER: Song YN 

PROVIDER: S-EPMC6644044 | biostudies-literature | 2018 Nov

REPOSITORIES: biostudies-literature