Diverse Lanthanide Coordination Polymers with 3,3'-Dimethylcyclopropane-1,2-dicarboxylate Ligand: Synthesis, Crystal Structure, and Properties.

ABSTRACT: In an attempt to investigate the influence of many variables on the synthesis of lanthanide coordination polymers (Ln-CPs) assembled from the ligand 3,3-dimethylcyclopropane-1,2-dicarboxylic acid, three different Ln-CPs with formulae [La₉(μ₄-dcd)₁₂(μ₃-O)₂(H)] _n (1), [Gd₄(μ₄-dcd)₆(H₂O)] _n (2), and [Gd₂(μ₃-OH)₂(μ₃-dcd)(μ₂-ac)₂(H₂O)] _n (3) (dcd = 3,3-dimethylcyclopropane-1,2-dicarboxylate, ac = acetate) have been hydrothermally synthesized and structurally characterized by elemental analysis, IR spectrum, thermal analysis, powder X-ray diffractio

SUBMITTER: Shi Y 

PROVIDER: S-EPMC6644930 | biostudies-literature | 2018 Sep

REPOSITORIES: biostudies-literature