Synthesis, Photophysics, and Switchable Luminescence Properties of a New Class of Ruthenium(II)-Terpyridine Complexes Containing Photoisomerizable Styrylbenzene Units.

ABSTRACT: We report here the synthesis and structural characterization of a new class of homoleptic terpyridine complexes of Ru(II) containing styrylbenzene moieties to improve room-temperature luminescence properties. Solid-state structure determination of 2 was done through single-crystal X-ray diffraction. Tuning of photophysical properties was done by incorporating both electron-donating and electron-withdrawing substituents in the ligand. The complexes exhibit strong emission having lifetimes in the range of 10.0-158.5 ns, dependent on the substituent and the solvent. Good correlations were also observed between Hammett σ_p parameters with the lifetimes of the complexes. Styrylbenzene moieties in the complexes induce trans-trans to trans-cis isomerization accompanied by huge al

SUBMITTER: Pal P 

PROVIDER: S-EPMC6645016 | biostudies-literature | 2018 Oct

REPOSITORIES: biostudies-literature