Effective Photocatalytic Hydrogen Evolution by Cascadal Carrier Transfer in the Reverse Direction.

ABSTRACT: Visible-light-responsive photocatalysts used in the highly efficient hydrogen production exhibit several disadvantages such as photocorrosion and fast recombination. Because of the potential important applications of such catalysts, it is crucial that a simple, effective solution is developed. In this respect, in this study, we combined SiC (β modification) and TiO₂ with CdS to overcome the challenges of photocorrosion and fast recombination of CdS. Notably, we found that when irradiated with visible light, CdS was excited, and the excited electrons moved to the conduction band of TiO₂, thereby increasing the efficiency of charge separation. In addition, by moving the holes generated on CdS to the valence band of SiC, in the opposite direction of TiO₂, phot

SUBMITTER: Nagakawa H 

PROVIDER: S-EPMC6645024 | biostudies-literature | 2018 Oct

REPOSITORIES: biostudies-literature