Supramolecular Organoplatinum(IV) Chemistry: Dimers and Polymers Formed by Intermolecular Hydrogen Bonding.

ABSTRACT: The reaction of [PtMe₂(6-dppd)], 1, where 6-dppd is a 1,4-bis(2-pyridyl)pyridazine derivative, with bromoalkanes BrCH₂R, having a hydrogen-bond donor group R, gave the corresponding chiral products of trans oxidative addition [PtBrMe₂(CH₂R)(6-dppd)], 2a, R = CO₂H; 3, R = 4-C₆H₄CO₂H; 4, R = 4-C₆H₄CH₂CO₂H; 7, R = 2-C₆H₄CH₂OH; 8, R = 4-C₆H₄B(OH)₂; 9, R = 3-C₆H₄B(OH)₂; and 10, R = 2-C₆H₄B(OH)₂. Complex 2a was formed in equilibrium with two isomers formed by cis oxidative a

SUBMITTER: McCready MS 

PROVIDER: S-EPMC6645029 | biostudies-literature | 2018 Oct

REPOSITORIES: biostudies-literature