Orthometalated N-(Benzophenoxazine)-o-aminophenol: Phenolato versus Phenoxyl States.

ABSTRACT: The molecular and electronic structures of the orthometalated ruthenium(III) and osmium(III) complexes of N-(benzophenoxazine)-o-aminophenol (^OXLH₂) that exhibits versatile redox activities are reported. The redox chemistry of ^OXLH₂ is remarkably different from that of N-(aryl)-o-aminophenol (^APLH₂). The study established that ^OXLH₂ is redox noninnocent and is a precursor of a phenoxyl radical. One of the C-H bonds of ^OXLH₂ is activated by ions, and ^OXLH₂ reveals three different redox states as dianionic phenolato (^OXL^2-), monoanionic phenoxyl radical (^OXL^•-), and zwitterionic phenoxium ca

SUBMITTER: Mondal S 

PROVIDER: S-EPMC6645054 | biostudies-literature | 2018 Oct

REPOSITORIES: biostudies-literature