Liquid-like Poly(ionic liquid) as Electrolyte for Thermally Stable Lithium-Ion Battery.

ABSTRACT: A liquid-like poly(ionic liquid) (PIL) with a very low glass transition temperature of -51 °C and a thermal decomposition temperature of 202.7 °C was synthesized. A PIL-based electrolyte by mixing this poly(ionic liquid) with additives of 10 wt % propylene carbonate and 0.1 M LiClO₄ is proved to be an excellent electrolyte for lithium-ion battery. The obtained PIL-based electrolyte exhibits a high ionic conductivity of 8.3 × 10^-5 S cm^-1 at 25 °C and 2.0 × 10^-4 S cm^-1 at 60 °C and a wide electrochemical potential window up to 5.61 V at 25 °C and 4.14 V at 60 °C. The Li/LiFePO₄ batteries equipped with this PIL-based electrolyte achieve high capacity, outstanding cycling stability and rate capability at 25 °C, and even improved

SUBMITTER: Zhang Z 

PROVIDER: S-EPMC6645412 | biostudies-literature | 2018 Sep

REPOSITORIES: biostudies-literature