Structural, Optical, Magnetic, and Dielectric Properties in Hybrid Solid Solutions of Zn_αNi_1-α(en)₃Ag₂I₄ (0 < α < 1) by Varying the Relative Zn/Ni Content.

ABSTRACT: The hybrids of M(en)₃Ag₂I₄ (M = Zn or Ni) are isostructural to each other and crystallize in space group P6₃22 with quite similar lattice parameters. The hybrid solid solutions Zn_αNi_1-α(en)₃Ag₂I₄ (0 < α < 1) have been prepared via self-assembly in the mixed N,N-dimethylformamide solution of AgNO₃, KI, and ethylenediamine, meanwhile, with certain relative amount of [Zn(en)₃]²⁺ and [Ni(en)₃]²⁺ ions at ambient condition. All hybrid solid solutions are isostructural to the parent hybrids M(en)₃Ag₂I₄ (M = Zn or Ni). The UV-vis-near IR diffuse reflection spectra in solid state, thermogravime

SUBMITTER: Xue C 

PROVIDER: S-EPMC6645538 | biostudies-literature | 2018 Sep

REPOSITORIES: biostudies-literature