Structural Diversity in Supramolecular Organization of Anionic Phosphate Monoesters: Role of Cations.

ABSTRACT: Syntheses and structures of anionic arylphosphate monoesters [ArOP(O)₂(OH)]^- (Ar = 2,6-CHPh₂-4-R-C₆H₂; R = Me/Et/iPr/tBu) with different counter cations are reported. The counter cations were varied systematically: imidazolium cation, 2-methyl imidazolium cation, N-methyl imidazolium cation, N,N'-alkyl substituted imidazolium cation, 1,4-diazabicyclo[2.2.2]octan-1-ium cation, 4,4'-bipyridinium dication, and magnesium(II) dication. The objective was to examine if the supramolecular structure of anionic arylphosphate monoesters could be modulated by varying the cation. It was found that an eight-membered P₂O₄H₂-hydrogen-bonded dimeric motif involving intermolecular H-bon

SUBMITTER: Santra B 

PROVIDER: S-EPMC6648147 | biostudies-literature | 2019 Jan

REPOSITORIES: biostudies-literature