DBU-Mediated Addition of α-Nitroketones to α-Cyano-enones and α,β-Unsaturated α-Ketoesters: Synthesis of Dihydrofurans and Conjugated Dienes.

ABSTRACT: 1,8-Diazabicyclo[5.4.0]undec-7-ene-mediated reactions of α-nitroketones with α-cyano-enones and α,β-unsaturated α-ketoesters have been developed. The products, namely, dihydrofurans and conjugated dienes, were isolated in moderate to good yields, and a range of substitutions were tolerated.

SUBMITTER: Sahoo SC 

PROVIDER: S-EPMC6648157 | biostudies-literature | 2019 Feb

REPOSITORIES: biostudies-literature