Reactions of (Arylimido)vanadium(V)-Trialkyl Complexes with Phenols: Effects of Arylimido Ligands and Phenols for Formation of the Vanadium Phenoxides.

ABSTRACT: Reactions of a series of (arylimido)vanadium(V) trialkyl complexes, V(NAr')(CH₂SiMe₃)₃ (Ar' = C₆H₅, 2-MeC₆H₄, 2,6-Me₂C₆H₃, 2,6-Cl₂C₆H₃), with various phenols (ArOH, Ar = 2,6-F₂C₆H₃, 2,6-Cl₂C₆H₃, 2,6-Me₂C₆H₃, 2,6- ⁱ Pr₂C₆H₃, 2- ^t BuC₆H₄, 2,6- ^t Bu₂C₆H₃; 1.0 equiv) affording V(NAr')(CH₂SiMe₃)₂(OAr) were conducted in C₆D₆ at 25 °C, and the effects of both arylim

SUBMITTER: Hayashibara H 

PROVIDER: S-EPMC6648231 | biostudies-literature | 2019 Mar

REPOSITORIES: biostudies-literature