Hybrid Supramolecules for Azolium-Linked Cyclophane Immobilization and Conformation Study: Synthesis, Characterization, and Photocatalytic Degradation.

ABSTRACT: In this paper, one imidazole macrocyclic divalent cation with a flexible configuration was chosen with the aim of the immobilization of its conformation. Six novel organic-inorganic hybrid supramolecules {([syn/anti-did](CdI₄)(C₂H₃N)} (1), {([syn/anti-did](HgI₄)(C₂H₃N)} (2), {([syn/syn-did](Pb₂I₈)(PbI₅)} (3), {([syn/syn-did](Bi₂I₈)(BiI₅)} (4), {([syn/syn-did](Ag₄Br₆)} _n (5), and {([syn/anti-did](Ag₂I₄)} (6) [did²⁺ = (1²z, 5²z)-1¹H, 5¹H-1, 5(1, 3)-diimidazol-3-iuma-3, 7(1, 2)-dibenzenacyclooctaphane-1

SUBMITTER: Li YY 

PROVIDER: S-EPMC6648278 | biostudies-literature | 2019 Mar

REPOSITORIES: biostudies-literature