Role of NiMo Alloy and Ni Species in the Performance of NiMo/Alumina Catalysts for Hydrodeoxygenation of Stearic Acid: A Kinetic Study.

ABSTRACT: The hydrodeoxygenation (HDO) of vegetable oil and fatty acid is extremely important for the sustainable production of diesel-range hydrocarbons. The present work depicts the role of Ni/Mo (mole) in the performance of alumina-supported NiMo catalysts for the HDO of stearic acid. Both Ni and NiMo alloy coexist in the NiMo catalysts depending on the Ni and Mo content. With increasing Ni/Mo (mole), the NiMo alloy content in the catalyst increases with the simultaneous decrease in the Ni content. The activity of NiMo catalysts thus enhances with increasing Ni/Mo (mole). The reaction follows a decarbonylation route over Ni sites and a HDO route over NiMo alloy species. C₁₇ and C₁₈ alkanes are thus observed as the dominating hydrocarbon product over Ni and NiMo alloy-rich ca

SUBMITTER: Kumar P 

PROVIDER: S-EPMC6648365 | biostudies-literature | 2019 Feb

REPOSITORIES: biostudies-literature