Mechanism of Thermal Degradation-Induced Gel Formation in Polyamide 6/Ethylene Vinyl Alcohol Blend Nanocomposites Studied by Time-Resolved Rheology and Hyphenated Thermogravimetric Analyzer Fourier Transform Infrared Spectroscopy Mass Spectroscopy: Synergistic Role of Nanoparticles and Maleic-anhydride-Grafted Polypropylene.

ABSTRACT: In this study, polyamide 6 (PA) is blended with ethylene vinyl alcohol (EVOH) to yield packaging materials with a balance of mechanical and gas barrier properties. However, the formation of gel-like structures in both polymers because of thermal degradation at high temperatures leads to a processing challenge, particularly during thin-gauge film extrusion. To address this challenge, nanoclays are introduced either directly or via a masterbatch of maleic-anhydride-grafted polypropylene to the PA/EVOH blend and time-resolved rheometry is used to study the effect of different modes of nanoclay incorporation on the kinetics of thermo-oxidative degradation of PA/EVOH blend and its nanocomposites. Time-resolved rheometry measurements allow the acquisition of accurate frequency-dependent linear v

SUBMITTER: Salehiyan R 

PROVIDER: S-EPMC6648533 | biostudies-literature | 2019 May

REPOSITORIES: biostudies-literature