Downconversion Luminescence-Based Nanosensor for Label-Free Detection of Explosives.

ABSTRACT: We report a selective and sensitive nanosensor probe based on polyethylenimine (PEI)-capped downconverting nanophosphors β-NaYF₄:Gd³⁺,Tb³⁺@PEI for the detection of 2,4,6-trinitrotoluene (TNT), both in water and buffer media. These downconverting phosphors were synthesized via a hydrothermal route and are known to show excellent chemical, thermal, and photostability. They emit sharp emission peaks centered at ∼488, 544, 584, and 619 nm, among which the peak at ∼544 nm was remarkably quenched (∼90%) by the addition of TNT without giving any new emission peak. The sensing mechanism is based on the formation of a Meisenheimer complex between the electron-rich amine-functionalized β-NaYF₄:Gd³⁺,Tb³⁺ nanophosphors and electron-defi

SUBMITTER: Malik M 

PROVIDER: S-EPMC6648544 | biostudies-literature | 2019 Feb

REPOSITORIES: biostudies-literature