Phase Control in Hafnia: New Synthesis Approach and Convergence of Average and Local Structure Properties.

ABSTRACT: Technologically relevant tetragonal/cubic phases of HfO₂ can be stabilized at room temperature by doping with trivalent rare earths using various approaches denoted generically as bulk coprecipitation. Using in situ/ex situ X-ray diffraction (XRD), Raman spectroscopy, high-resolution transmission electron microscopy, and in situ/ex situ site-selective, time-gated luminescence spectroscopy, we show that wet impregnation of hafnia nanoparticles with 10% Eu oxide followed by mild calcination in air at 500 °C produces an efficient stabilization of the cubic phase, comparable to that obtained by bulk precipitation. The physical reasons behind the apparently conflictual data concerning the actual crystallographic phase and the local symmetry around the Eu stabilizer and how these can

SUBMITTER: Cojocaru B 

PROVIDER: S-EPMC6648616 | biostudies-literature | 2019 May

REPOSITORIES: biostudies-literature