Models for Cooperative Catalysis: Oxidative Addition Reactions of Dimethylplatinum(II) Complexes with Ligands Having Both NH and OH Functionality.

ABSTRACT: The role of NH and OH groups in the oxidative addition reactions of the complexes [PtMe₂(κ²-N,N'-L)], L = 2-C₅H₄NCH₂NH-x-C₆H₄OH [3, x = 2, L = L1; 4, x = 3, L = L2; 5, x = 4, L = L3], has been investigated. Complex 3 is the most reactive. It reacts with CH₂Cl₂ to give a mixture of isomers of [PtMe₂(CH₂Cl)(κ³-N,N',O-(L1-H)], 6, and decomposes in acetone to give [PtMe₃(κ³-N,N',O-(L1-H)], 7, both of which contain the fac tridentate deprotonated liga

SUBMITTER: Azizpoor Fard M 

PROVIDER: S-EPMC6648696 | biostudies-literature | 2019 Jan

REPOSITORIES: biostudies-literature