Twofold Porosity and Surface Functionalization Effect on Pt-Porous GaN for High-Performance H₂-Gas Sensors at Room Temperature.

ABSTRACT: The achievement of H₂ detection, up to 25 ppm, at room temperature using sulfur-treated, platinum (Pt)-decorated porous GaN is reported in this study. This achievement is attributed to the large lateral pore size, Pt catalyst, and surface treatment using organic sulfide. The performance of H₂-gas sensors is studied as a function of the operating temperature by providing an adsorption activation energy of 22 meV at 30 ppm H₂, confirming the higher sensitivity of the sulfide-treated Pt-porous GaN sensor. Furthermore, the sensing response of the sulfide-treated Pt-porous GaN gas sensor increases with the increase in porosity (surface-to-volume ratio) and pore radii. Using the Knudsen diffusion-surface reaction equation, the H₂ gas concentration prof

SUBMITTER: Shafa M 

PROVIDER: S-EPMC6648823 | biostudies-literature | 2019 Jan

REPOSITORIES: biostudies-literature