Photocatalytic and Ferric Ion Sensing Properties of a New Three-Dimensional Metal-Organic Framework Based on Cuboctahedral Secondary Building Units.

ABSTRACT: A new three-dimensional microporous metal-organic framework based on Zn(II) clusters with the formula {[Zn₇(NDC)_5.5(μ₄-OH)₃]·7DMF} _n (1) (H₂NDC = 1,4-naphthalenedicarboxylic acid) had been synthesized and characterized. The MOF 1 displays an uncommon bsn topology, which is based on a unique heptanuclear Zn₇(OH)₃(CO₂)₁₁ cluster as a secondary building unit. The MOF had been employed as a photocatalyst for the photodegradation of model organic dyes rhodamine B and methyl violet in light. The results of photocatalytic experiments showed that 1 can successfully be employed as the photocatalyst for the benign decomposition of these dyes. A mechanism for the p

SUBMITTER: Ding Q 

PROVIDER: S-EPMC6649122 | biostudies-literature | 2019 Jun

REPOSITORIES: biostudies-literature