Thermodynamic Properties and Crystallographic Characterization of Semiclathrate Hydrates Formed with Tetra-n-butylammonium Glycolate.

ABSTRACT: Semiclathrate hydrates are a crystalline host-guest material, which forms with water and ionic substances such as tetra-n-butylammonium (TBA) salts. Various anions can be used as a counter anion to the TBA cation, and they can modify thermodynamic properties of the semiclathrate hydrates, which are critical for applications, for example, cold energy storage and gas separation. In this study, the semiclathrate hydrates of the TBA glycolate were newly synthesized. Measurements for melting temperatures and a heat of fusion and a crystal structure analysis were performed. In comparison with the other similar materials, such as acetates, propionates, lactates, and hydroxybutyrates, the glycolate greatly changed the melting temperature and the heat of fusion. The preliminarily determined

SUBMITTER: Muromachi S 

PROVIDER: S-EPMC6649264 | biostudies-literature | 2019 Apr

REPOSITORIES: biostudies-literature