Structural and Thermal Studies of New Triphenyltin Complexes.

ABSTRACT: Crystal and molecular structures of new triorganotin complexes have been determined via X-ray diffraction. These complexes include, among others, the second polymorph of Ph₃Sn(thiocytosine), the double complex salt Ph₃Sn(methimazole)₂·Ph₃SnCl₂, and five-coordinated triphenyltin chloride with methimazole, tetrahydopyrimidine-2-thione, dimethylformamide, and dimethyl sulfoxide. Hirshfeld surface analysis allowed for better visualization and precise pinpointing of the differences between polymorphs as well as easier analysis of intermolecular interactions. All of the new structure of the Ph₃Sn(L)Cl type displayed interesting thermal features and therefore were also analyzed via thermogravimetric analysis/simultaneous thermal an

SUBMITTER: Owczarzak A 

PROVIDER: S-EPMC6649270 | biostudies-literature | 2019 Jun

REPOSITORIES: biostudies-literature