Crystal structure of tetra-kis-[μ-3-carboxy-1-(1,2,4-triazol-4-yl)adamantane-κ² N ¹:N ²]tetra-fluoridodi-μ₂-oxido-dioxidodisilver(I)divanadium(V) tetra-hydrate.

ABSTRACT: The crystal structure of the title mol-ecular complex, [Ag₂{VO₂F₂}₂(C₁₃H₁₇N₃O₂)₄]·4H₂O, supported by the heterofunctional ligand tr-ad-COOH [1-(1,2,4-triazol-4-yl)-3-carb-oxy-adamantane] is reported. Four 1,2,4-triazole groups of the ligand link two Ag^I atoms, as well as Ag^I and V^V centres, forming the heterobimetallic coordination cluster {Ag^I ₂(V^VO₂F₂)₂(tr)₄}. V^V exists as a vanadium oxofluoride anion and possesses a distorted trigonal-bipyramidal coordination environment [VO₂F₂N]. A carb-oxy-lic acid functional group of the

SUBMITTER: Senchyk GA 

PROVIDER: S-EPMC6658938 | biostudies-literature | 2019 Jun

REPOSITORIES: biostudies-literature