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Bis[μ-bis-(2,6-diiso-propyl-phen-yl) phosphato-κ² O:O']bis-[(2,2'-bi-pyridine-κ² N,N')lithium] toluene disolvate and its catalytic activity in ring-opening polymerization of ∊-caprolactone and l-dilactide.

ABSTRACT: The solvated centrosymmmtric title compound, [Li₂(C₂₄H₃₄O₄P)₂(C₁₀H₈N₂)₂]·2C₇H₈, was formed in the reaction between {Li[(2,6-ⁱPr₂C₆H₃-O)₂POO](MeOH)₃}(MeOH) and 2,2'-bi-pyridine (bipy) in toluene. The structure has monoclinic (P2₁/n) symmetry at 120 K and the asymmetric unit consists of half a complex mol-ecule and one mol-ecule of toluene solvent. The diaryl phosphate ligand demonstrates a μ-κO:κO'-bridging coordination mode and the 2,2'-bi-pyridine ligand is chelating to the Li⁺ cation, generating a distorted tetra-hedral LiN₂O₂ coordi

SUBMITTER: Kalugin AE

PROVIDER: S-EPMC6658944 | biostudies-literature | 2019 Jun

REPOSITORIES: biostudies-literature

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Bis[μ-bis-(2,6-diiso-propyl-phen-yl) phosphato-κ² O:O']bis-[(2,2'-bi-pyridine-κ² N,N')lithium] toluene disolvate and its catalytic activity in ring-opening polymerization of ∊-caprolactone and l-dilactide.

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Dataset Information

Bis[μ-bis-(2,6-diiso-propyl-phen-yl) phosphato-κ2 O:O']bis-[(2,2'-bi-pyridine-κ2 N,N')lithium] toluene disolvate and its catalytic activity in ring-opening polymerization of ∊-caprolactone and l-dilactide.

OmicsDI is part of the ELIXIR infrastructure

Tweets

Bis[μ-bis-(2,6-diiso-propyl-phen-yl) phosphato-κ² O:O']bis-[(2,2'-bi-pyridine-κ² N,N')lithium] toluene disolvate and its catalytic activity in ring-opening polymerization of ∊-caprolactone and l-dilactide.