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Crystal structure of 7,8,15,16,17-penta-thiadi-spiro-[5.2.5⁹.3⁶]hepta-deca-ne.

ABSTRACT: The title compound, C₁₂H₂₀S₅, crystallizes in the monoclinic space group P2₁/c with four mol-ecules in the unit cell. In the crystal, the asymmetric unit comprises the entire mol-ecule with the three cyclic moieties arranged in a line. The mol-ecules in the unit cell pack in a parallel fashion, with their longitudinal axes arranged along a uniform direction. The packing is stabilized by the one-dimensional propagation of non-classical hydrogen-bonding contacts between the central sulfur atom of the S₃ fragment and the C-H of a cyclo-hexyl group from a glide-related mol-ecule [C⋯S = 3.787 (2) Å].

SUBMITTER: Hofstetter R

PROVIDER: S-EPMC6658967 | biostudies-literature | 2019 Jun

REPOSITORIES: biostudies-literature

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Crystal structure of 7,8,15,16,17-penta-thiadi-spiro-[5.2.59.36]hepta-deca-ne.

Hofstetter Robert R Elvers Benedict J BJ Potlitz Felix F Link Andreas A Schulzke Carola C

Acta crystallographica. Section E, Crystallographic communications 20190524 Pt 6

The title compound, C12H20S5, crystallizes in the monoclinic space group P21/c with four mol-ecules in the unit cell. In the crystal, the asymmetric unit comprises the entire mol-ecule with the three cyclic moieties arranged in a line. The mol-ecules in the unit cell pack in a parallel fashion, with their longitudinal axes arranged along a uniform direction. The packing is stabilized by the one-dimensional propagation of non-classical hydrogen-b ...[more]

PMID: 31391988

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