Electronic spectroscopy and nanocalorimetry of hydrated magnesium ions [Mg(H₂O)_n]⁺, n = 20-70: spontaneous formation of a hydrated electron?

ABSTRACT: Hydrated singly charged magnesium ions [Mg(H2O)n]+ are thought to consist of an Mg2+ ion and a hydrated electron for n > 15. This idea is based on mass spectra, which exhibit a transition from [MgOH(H2O)n-1]+ to [Mg(H2O)n]+ around n = 15-22, black-body infrared radiative dissociation, and quantum chemical calculations. Here, we present photodissociation spectra of size-selected [Mg(H2O)n]+ in the range of n = 20-70 measured for photon energies of 1.0-5.0 eV. The spectra exhibit a broad absorption from 1.4 to 3.2 eV, with two local maxima around 1.7-1.8 eV and 2.1-2.5 eV, depending on cluster size. The spectra shift slowly from n = 20 to n = 50, but no significant change is observed for n = 50-70. Quantum chemical modeling of the spectra yields several candidates for the observed absorption

SUBMITTER: Taxer T 

PROVIDER: S-EPMC6677030 | biostudies-literature | 2019 Jul

REPOSITORIES: biostudies-literature