Construction of stabilized bulk-nano interfaces for highly promoted inverse CeO₂/Cu catalyst.

ABSTRACT: As the water-gas shift (WGS) reaction serves as a crucial industrial process, strategies for developing robust WGS catalysts are highly desiderated. Here we report the construction of stabilized bulk-nano interfaces to fabricate highly efficient copper-ceria catalyst for the WGS reaction. With an in-situ structural transformation, small CeO₂ nanoparticles (2-3 nm) are stabilized on bulk Cu to form abundant CeO₂-Cu interfaces, which maintain well-dispersed under reaction conditions. This inverse CeO₂/Cu catalyst shows excellent WGS performances, of which the activity is 5 times higher than other reported Cu catalysts. Long-term stability is also very solid under harsh conditions. Mechanistic study illustrates that for the inverse CeO₂/Cu catalyst,

SUBMITTER: Yan H 

PROVIDER: S-EPMC6677889 | biostudies-literature | 2019 Aug

REPOSITORIES: biostudies-literature