Oxygen-Resistant Electrochemiluminescence System with Polyhedral Oligomeric Silsesquioxane.

ABSTRACT: We report the oxygen-resistant electrochemiluminescence (ECL) system from the polyhedral oligomeric silsesquioxane (POSS)-modified tris(2,2'-bipyridyl)ruthenium(II) complex (Ru-POSS). In electrochemical measurements, including cyclic voltammetry (CV), it is shown that electric current and ECL intensity increase in the mixture system containing Ru-POSS and tripropylamine (TPrA) on the indium tin oxide (ITO) working electrode. The lower onset potential (E_onset) in CV is observed with Ru-POSS compared to tris(2,2'-bipyridyl)ruthenium(II) complex (Ru(bpy)₃²⁺). From the series of mechanistic studies, it was shown that adsorption of Ru-POSS onto the ITO electrode enhances TPrA oxidation and subsequently the efficiency of ECL with lower voltage. Moreover, o

SUBMITTER: Nakamura R 

PROVIDER: S-EPMC6680606 | biostudies-literature | 2019 Jul

REPOSITORIES: biostudies-literature