Copolymerization of Norbornene and Styrene with Anilinonaphthoquinone-Ligated Nickel Complexes.

ABSTRACT: Poly(norbornene-co-styrene)s were synthesized by the use of anilinonaphthoquinone-ligated nickel complexes [Ni(C₁₀H₅O₂NAr)(Ph)(PPh₃): 1a, Ar = C₆H₃-2,6-ⁱPr; 1b, Ar = C₆H₂-2,4,6-Me; 1c, Ar = C₆H₅] activated with modified methylaluminoxane (MMAO) or B(C₆F₅)₃ in toluene. The effects of the cocatalysts were more significant than those of the nickel complexes, and MMAO gave higher activity than B(C₆F₅)₃. The structural characterizations of the products indicated the formation of statistical norbornene copolymers. An increase of the styrene ratio in feed led to an increase in the inco

SUBMITTER: Chowdhury SI 

PROVIDER: S-EPMC6680643 | biostudies-literature | 2019 Jun

REPOSITORIES: biostudies-literature