Construction of Chiral Nanoassemblies Based on Host-Guest Complexes and Their Responsive CD and CPL Properties: Chirality Transfer From 2,6-helic[6]arenes to a Stilbazolium Derivative.

ABSTRACT: A couple of water-soluble chiral 2,6-helic[6]arene derivatives P -H1 and M -H1 were synthesized, and they could form 1:1 stable complexes with 4-[(4'-N, N-diphenylamino)-styryl]-N-methylpyridinium iodide (G) in water. Compared with G, the host-guest complexes exhibited enhanced fluorescence, which might be attributed to the spatial confinement of G and restriction of aggregation-caused quenching (ACQ) effects. Based on the host-guest complexation, the first helic[6]arene-based chiral assemblies were then constructed, and they showed rectangular or hexagonal nanostructures by scanning electron microscopy (SEM) images. Interestingly, the assemblies showed clear mirror-image circular dichroism (CD) and circularly pol

SUBMITTER: Guo Y 

PROVIDER: S-EPMC6688524 | biostudies-literature | 2019

REPOSITORIES: biostudies-literature